A New Quassinoid from Brucea javanica

Chemistry of Natural Compounds - A new quassinoid, dehydrobruceantinol B (1), was isolated from the seeds of Brucea javanica, together with two known compounds, bruceantinol (2) and bruceine A (3)....     

Facile fabrication of oxygen-doped carbon nitride with enhanced visible-light photocatalytic degradation of methyl mercaptan

Research on Chemical Intermediates - Element doping has demonstrated an effective strategy for enhancing photocatalytic performance of carbon nitride (CN). Herein, we reported that oxygen-doped CN...     

Direct Synthesis of Adipic Esters and Adiponitrile via Photoassisted Cobalt-Catalyzed Alkene Hydrodimerization

The direct hydrodimerization of acrylates and acrylonitrile offers a general streamlined access to industrially important intermediates to nylon 6,6. However, a practical catalytic method for this process has thus far underdeveloped owing to the challenges in regioselectivity and environmental compatibility of applied reagents. Here, we report a cobalt-catalyzed tail-to-tail hydrodimerization of activated alkenes driven by a visible-light photoredox catalysis at ambient temperature, which is applicable to both adipates and adiponitrile synthesis from potentially renewable feedstocks. This protocol utilizes half equivalent of hantzsch ester as a recyclable two-electron and two-proton donor with the assistance of catalytic amount of base as a proton shuttle, and has been shown to be highly regioselective and efficient for hydrodimerizing various activated alkenes to 1,4-difunctionalized butane derivatives.     

Graphene Saturable Absorber Mirror for Mode-Locked Orange Pulse Laser

Journal of Russian Laser Research - We demonstrate a passively-mode-locked Pr3+: LuLiF4 laser operated at the 604 nm orange wave-length, using monolayer graphene as a saturable absorber. The...     

Bidirectional and Unidirectional Negative Differential Thermal Resistance Effect in a Modified Lorentz Gas Model

Recently,the negative differential thermal resistance effect was discovered in a homojunction made of a negative thermal expansion material,which is very promising for realizing macroscopic thermal transistors.Similar to the Monte Carlo phonon simulation to deal with grain boundaries,we introduce positive temperature-dependent interface thermal resistance in the modified Lorentz gas model and find negative differential thermal resistance effect.In the homojunction,we reproduce a pair of equivalent negative differential thermal resistance effects in different temperature gradient directions.In the heterojunction,we realize the unidirectional negative differential thermal resistance effect,and it is accompanied by the super thermal rectification effect.Using this new way to achieve high-performance thermal devices is a new direction,and will provide extensive reference and guidance for designing thermal devices.     

Composite chattering-free discrete-time sliding mode controller design for active front steering system of electric vehicles

Nonlinear Dynamics - In order to reduce the adverse effects of internal uncertainty and external disturbance in the active front steering (AFS) system of electric vehicles, two chattering-free...     

Output feedback regulation of large-scale feedforward systems with discrete and distributed delays

Nonlinear Dynamics - This paper proposes an output feedback control strategy to achieve the global regulation of a class of large-scale feedforward nonlinear systems with discrete and distributed...     

Study on the static properties of spiral springs under static loading

Applied Mathematics and Mechanics - Spiral springs have a wide range of applications in various fields. As a result of the complexity of friction, few theoretical analyses of spring belts under...     

The dual form of Beck type identities

The Ramanujan Journal - Inspired by Andrews and Merca’s recent work on the number of even parts over all partitions into distinct parts, we introduce a new kind of Beck type identities, which...